gave him their medal, while the Academies of Paris and St. Petersburg
conferred their membership upon him. Edinburgh had made him an honorary
doctor of laws at an early period of his career; but, I need hardly
add, that a man of Priestley's opinions received no recognition from
the universities of his own country.
That Priestley's contributions to the knowledge of chemical fact were
of the greatest importance, and that they richly deserve all the praise
that has been awarded to them, is unquestionable; but it must, at the
same time, be admitted that he had no comprehension of the deeper
significance of his work; and, so far from contributing anything to the
theory of the facts which he discovered, or assisting in their rational
explanation, his influence to the end of his life was warmly exerted in
favour of error. From first to last, he was a stiff adherent of the
phlogiston doctrine which was prevalent when his studies commenced;
and, by a curious irony of fate, the man who by the discovery of what
he called "dephlogisticated air" furnished the essential datum for the
true theory of combustion, of respiration, and of the composition of
water, to the end of his days fought against the inevitable corollaries
from his own labours. His last scientific work, published in 1800,
bears the title, "The Doctrine of Phlogiston established, and that of
the Composition of Water refuted."
When Priestley commenced his studies, the current belief was, that
atmospheric air, freed from accidental impurities, is a simple
elementary substance, indestructible and unalterable, as water was
supposed to be. When a combustible burned, or when an animal breathed
in air, it was supposed that a substance, "phlogiston," the matter of
heat and light, passed from the burning or breathing body into it, and
destroyed its powers of supporting life and combustion. Thus, air
contained in a vessel in which a lighted candle had gone out, or a
living animal had breathed until it could breathe no longer, was called
"phlogisticated." The same result was supposed to be brought about by
the addition of what Priestley called "nitrous gas" to common air.
In the course of his researches, Priestley found that the quantity of
common air which can thus become "phlogisticated," amounts to about
one-fifth the volume of the whole quantity submitted to experiment.
Hence it appeared that common air consists, to the extent of
four-fifths of its volume, of air which is already "phlogisticated";
while the other fifth is free from phlogiston, or "dephlogisticated."
On the other hand, Priestley found that air "phlogisticated" by
combustion or respiration could be "dephlogisticated," or have the
properties of pure common air restored to it, by the action of green
plants in sunshine. The question, therefore, would naturally arise--as
common air can be wholly phlogisticated by combustion, and converted
into a substance which will no longer support combustion, is it
possible to get air that shall be less phlogisticated than common air,
and consequently support combustion better than common air does?
Now, Priestley says that, in 1774, the possibility of obtaining air
less phlogisticated than common air had not occurred to him. [6] But in
pursuing his experiments on the evolution of air from various bodies by
means of heat, it happened that, on the 1st of August 1774, he threw
the heat of the sun, by means of a large burning glass which he had
recently obtained, upon a substance which was then called _mercurius
calcinatus per se_, and which is commonly known as red precipitate.
"I presently found that, by means of this lens, air was expelled